The "Raging Bull" actor, who spent the day entangled in divorce proceedings with his estranged wife, Grace Hightower, became increasingly frustrated as he was swarmed by photographers and reporters while trying to locate the driver.
“You’re not in front!" he shouted into his phone. "You’re not where you dropped us off!”
Though De Niro's lawyer tried to usher him inside, the actor was not having it.
"Where are you? Where the f*** are you?" he yelled. "... I don't care if they chased you away."
De Niro and Hightower, who married in 1997, are fighting over custody of their daughter.